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Mechanical Recycling of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate)/Polylactide Based Blends - Journal of Polymers and the Environment

  • ️Grohens, Yves
  • ️Tue Jun 24 2014

Abstract

The effects of recycling cycles (up to six repeated cycles) on the structure and properties of neat poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), neat polylactide (PLA) and PHBV/PLA: 50/50 (wt%) blends elaborated by melt molding process were investigated. The changes in the chemical structure, the morphology and the thermal, mechanical and rheological properties of the recycled materials were studied. The reduction of molecular weights of both PHBV and PLA showed the predominance of chain scission mechanism as a result of degradation inducing an enhancement of PHBV chain mobility, as also revealed by the increasing of the PHBV crystallinity measured using differential scanning calorimetry and wide angle X-ray scattering. Nevertheless, all these effects were significantly smaller for neat PLA and PHBV–PLA blends compared to those of neat PHBV. Contrary to PLA, PHBV seems to be relatively more sensitive to the thermomechanical degradation and the presence of PLA in the PHBV–PLA blend tends to partially prevent the degradation of PHBV. Mechanical results evidenced the great recyclability of PHBV/PLA blends, even after six reprocessing cycles, since the values of mechanical characteristics remain more or less constant compared to the initial ones revealing the preservation of the material mechanical properties. A stabilizing effect of PLA on the recyclability of PHBV–PLA blends was highlighted and it can be concluded that the incorporation of PLA in PHBV/PLA blends might be a promising route to extend the PHBV applications.

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References

  1. Ramkumar DHS, Bhattacharya M (1998) Steady shear and dynamic properties of biodegradable polyesters. Polym Eng Sci 38:1426–1435

    Article  CAS  Google Scholar 

  2. Khanna S, Srivastava AK (2008) A simple structured mathematical model for biopolymer (PHB) production. Biotechnol Prog 21:830–838

    Article  Google Scholar 

  3. Deroiné M, Le Duigou A, Corre Y-M, Le Gac P-Y, Davies P, César G, Bruzaud S. Accelerated ageing of polylactide in aqueous environments: comparative study between distilled water and seawater. Polym Degrad Stab. doi:10.1016/j.polymdegradstab.2014.01.020

  4. Modi S, Koelling K, Vodovotz Y (2012) Miscibility of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with high molecular weight poly(lactic acid) blends determined by thermal analysis. J Appl Polym Sci 124:3074–3081

    Article  CAS  Google Scholar 

  5. Arrieta MP, López J, Hernández A, Rayón E (2014) Ternary PLA–PHB–Limonene blends intended for biodegradable food packaging applications. Eur Polym J 50:255–270

    Article  CAS  Google Scholar 

  6. Siracusa V, Rocculi P, Romani S, Rosa MD (2008) Biodegradable polymers for food packaging: a review. Trends Food Sci Technol 19:634–643

    Article  CAS  Google Scholar 

  7. Corre Y-M, Bruzaud S, Audic J-L, Grohens Y (2012) Morphology and functional properties of commercial polyhydroxyalkanoates: a comprehensive and comparative study. Polym Test 31:226–235

    Article  CAS  Google Scholar 

  8. Bruzaud S, Bourmaud A (2007) Thermal degradation and (nano)mechanical behavior of layered silicate reinforced poly(3-hydroxybutyrate-co-3-hydroxyvalerate) nanocomposites. Polym Test 26:652–659

    Article  CAS  Google Scholar 

  9. Zaidi L, Bruzaud S, Kaci M, Bourmaud A, Gautier N, Grohens Y (2013) The effects of gamma irradiation on the morphology and properties of polylactide/Cloisite 30B nanocomposites. Polym Degrad Stab 98:348–355

    Article  CAS  Google Scholar 

  10. Zaidi L, Bruzaud S, Bourmaud A, Médéric P, Kaci M, Grohens Y (2010) Relationship between structure and rheological, mechanical and thermal properties of polylactide/Cloisite 30B nanocomposites. J Appl Polym Sci 116:1357–1365

    CAS  Google Scholar 

  11. Raquez J-M, Habibi Y, Murariu M, Dubois P (2013) Polylactide (PLA)-based nanocomposites. Prog Polym Sci 38:1504–1542

    Article  CAS  Google Scholar 

  12. Zembouai I, Kaci M, Bruzaud S, Benhamida A, Corre Y-M, Grohens Y (2013) A study of morphological, thermal, rheological and barrier properties of poly(3-hydroxybutyrate-Co-3-hydroxyvalerate)/polylactide blends prepared by melt mixing. Polym Test 32:842–851

    Article  CAS  Google Scholar 

  13. Zembouai I, Bruzaud S, Kaci M, Benhamida A, Corre Y-M, Grohens Y et al (2014) Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/polylactide blends: thermal stability, flammability and thermo-mechanical behavior. J Polym Environ 22:131–139

    Article  CAS  Google Scholar 

  14. Zembouai I, Bruzaud S, Kaci M, Benhamida A, Corre Y-M, Grohens Y, et al (2013) Synergistic effect of compatibilizer and cloisite 30B on the functional properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/polylactide blends. Polym Eng Sci. doi:10.1002/j.polymengsci.23776

  15. Gerard T, Budtova T (2012) Morphology and molten-state rheology of polylactide and polyhydroxyalkanoate blends. Eur Polym J 48:1110–1117

    Article  CAS  Google Scholar 

  16. Pivsa-Art S, Srisawat N, O-Charoen N, Pavasupree S, Pivsa-Art W (2011) Preparation of knitting socks from Poly(Lactic Acid) and Poly[(R)-3-Hydroxybutyrate-co-(R)-3-Hydroxyvalerate] (PHBV) blends for textile industrials. Energy Procedia 9:589–597

    Article  CAS  Google Scholar 

  17. Yu L, Dean K, Li L (2006) Polymer blends and composites from renewable resources. Prog Polym Sci 31:576–602

    Article  CAS  Google Scholar 

  18. Boufarguine M, Guinault A, Miquelard-Garnier G, Sollogoub C (2013) PLA/PHBV films with improved mechanical and gas barrier properties. Macromol Mater Eng 298:1065–1073

    CAS  Google Scholar 

  19. Modi S, Koelling K, Vodovotz Y (2013) Assessing the mechanical, phase inversion, and rheological properties of poly-[(R)-3-hydroxybutyrate-co-(R)-3-hydroxyvalerate] (PHBV) blended with poly-(l-lactic acid) (PLA). Eur Polym J 49:3681–3690

    Article  CAS  Google Scholar 

  20. Zaverl M, Seydibeyoğlu MÖ, Misra M, Mohanty A (2012) Studies on recyclability of polyhydroxybutyrate-co-valerate bioplastic: multiple melt processing and performance evaluations. J Appl Polym Sci 125:324–331

    Article  Google Scholar 

  21. Le Duigou A, Pillin I, Bourmaud A, Davies P, Baley C (2008) Effect of recycling on mechanical behaviour of biocompostable flax/poly(l-lactide) composites. Compos Part Appl Sci Manuf 39:1471–1478

    Article  Google Scholar 

  22. Żenkiewicz M, Richert J, Rytlewski P, Moraczewski K, Stepczyńska M, Karasiewicz T (2009) Characterisation of multi-extruded poly(lactic acid). Polym Test 28:412–418

    Article  Google Scholar 

  23. Pillin I, Montrelay N, Bourmaud A, Grohens Y (2008) Effect of thermo-mechanical cycles on the physico-chemical properties of poly(lactic acid). Polym Degrad Stab 93:321–328

    Article  CAS  Google Scholar 

  24. Touati N, Kaci M, Bruzaud S, Grohens Y (2011) The effects of reprocessing cycles on the structure and properties of isotactic polypropylene/cloisite 15A nanocomposites. Polym Degrad Stab 96:1064–1073

    Article  CAS  Google Scholar 

  25. Remili C, Kaci M, Benhamida A, Bruzaud S, Grohens Y (2011) The effects of reprocessing cycles on the structure and properties of polystyrene/Cloisite15A nanocomposites. Polym Degrad Stab 96:1489–1496

    Article  CAS  Google Scholar 

  26. Kaci M, Remili C, Benhamida A, Bruzaud S, Grohens Y (2012) Recyclability of polystyrene/clay nanocomposites. Mol Cryst Liq Cryst 556:94–106

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are pleased to express their grateful acknowledgements to Dr. Isabelle Pillin, Dr. Mickael Castro, Dr. Abdelkader Bendahou, Antoine Kervoelen, Anthony Magueresse and Françoise Peresse for their help in the experimental work. The authors are grateful to EGIDE through the TASSILI program 12 MDU 871 for its financial support in this collaborative project.

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Authors and Affiliations

  1. Laboratoire d’Ingénierie des Matériaux de Bretagne (LIMATB), Université de Bretagne-Sud, Rue de Saint Maudé, 56321, Lorient Cedex, France

    Idris Zembouai, Stéphane Bruzaud, Yves-Marie Corre & Yves Grohens

  2. Laboratoire des Matériaux Polymères Avancés (LMPA), Faculté de Technologie, Université Abderrahmane Mira, 06000, Bejaïa, Algeria

    Idris Zembouai, Mustapha Kaci & Aida Benhamida

Authors

  1. Idris Zembouai

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  2. Stéphane Bruzaud

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  3. Mustapha Kaci

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  4. Aida Benhamida

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  5. Yves-Marie Corre

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  6. Yves Grohens

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Correspondence to Stéphane Bruzaud.

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Cite this article

Zembouai, I., Bruzaud, S., Kaci, M. et al. Mechanical Recycling of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate)/Polylactide Based Blends. J Polym Environ 22, 449–459 (2014). https://doi.org/10.1007/s10924-014-0684-5

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  • Published: 24 June 2014

  • Issue Date: December 2014

  • DOI: https://doi.org/10.1007/s10924-014-0684-5

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