General Zalesiite Information
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Chemical Formula: |
(Ca,Y)Cu6[(AsO4)2(AsO3OH)(OH)6]•3(H2O) |
Composition: |
Molecular Weight = 1,004.97 gm |
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Calcium 3.19 % Ca 4.46 % CaO |
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Yttrium 1.77 % Y 2.25 % Y2O3 |
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Copper 37.94 % Cu 47.49 % CuO |
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Arsenic 22.37 % As 34.31 % As2O5 |
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Hydrogen 1.30 % H 11.65 % H2O |
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Oxygen 33.43 % O |
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______ ______ |
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100.00 % 100.16 % = TOTAL OXIDE |
Empirical Formula: |
Ca0.8Y0.2Cu6(AsO4)2(AsO3OH)(OH)6•3(H2O) |
Environment: |
Oxidation product of chalcopyrite The calcium and arsenate dominant member of the mixite group. |
IMA Status: |
Approved IMA 1997 (Dana # Added) |
Locality: |
Zalesi (formerly Valdek) uranium deposit near Javornik, northern Moravia, Czech Republic. Link to MinDat.org Location Data. |
Name Origin: |
Named for the locality. |
Synonym: |
IMA1997-009 |
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Zalesiite Image |
Images:
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Images:
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Zalesiite Crystallography
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Axial Ratios: |
a:c = 1:0.43327 |
Cell Dimensions: |
a = 13.571, c = 5.88, Z = 2; V = 937.85 Den(Calc)= 3.56 |
Crystal System: |
Hexagonal - DipyramidalH-M Symbol (6/m) Space Group: P 63/m |
X Ray Diffraction: |
By Intensity(I/Io): 11.64(1), 2.9347(0.42), 4.431(0.41), |
Crystal Structure:
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Aruga A , Nakai I , Acta Crystallographica, Section C , 41 (1985) p.161-163, Structure of Ca-rich agardite,, (Ca0.40Y0.31Fe0.09Ce0.06La0.04Nd0.01)Cu6.19[(AsO4)2.42(HAsO4)0.49](OH)6.38*3H2O, Locality: Setoda, Hiroshima, Japan
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Physical Properties of Zalesiite
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Color: |
Pale green. |
Density: |
3.49 |
Diaphaneity: |
Transparent |
Habit: |
Acicular - Occurs as needle-like crystals. |
Habit: |
Fibrous - Crystals made up of fibers. |
Habit: |
Powdery - Forms a loose, poorly-coherent pulverulent mass. |
Hardness: |
2-3 - Gypsum-Calcite |
Luster: |
Vitreous - Resinous |
Streak: |
white |
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Optical Properties of Zalesiite
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Gladstone-Dale: |
CI meas= -0.101 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= -0.079 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2041,KPDmeas= 0.2082,KC= 0.1891 Ncalc = 1.66 - 1.67 |
Optical Data: |
Uniaxial (+), w=1.688, e=1.765, bire=0.0770. |
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Calculated Properties of Zalesiite
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Electron Density: |
Bulk Density (Electron Density)=3.39 gm/cc note: Specific Gravity of Zalesiite =3.56 gm/cc. |
Fermion Index: |
Fermion Index = 0.0002055013 Boson Index = 0.9997944987 |
Photoelectric: |
PEZalesiite = 34.66 barns/electron U=PEZalesiite x rElectron Density= 117.31 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Zalesiite is Not Radioactive |
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Zalesiite Classification
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Dana Class: |
42.05.01.04 (42)Hydrated Phosphates, etc., Containing Hydroxyl or Halogen |
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(42.05)where (A)2 (XO4) Zq · x(H2O) |
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(42.05.01)Mixite group (Arsenate Series) |
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42.05.01.01 Mixite BiCu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
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42.05.01.02 Agardite-(Y) (Y,Ca)Cu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
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42.05.01.02a Agardite-(La)! (La,Ca)Cu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
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42.05.01.02b Agardite-(Nd)! (Pb,Nd,Y,La,Ca)Cu6(AsO4)3(OH)6•3(H2O) 6/m |
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42.05.01.02c Agardite-(Dy)! (Dy,La,Ca)Cu6(AsO4)3(OH)6•3(H2O) 6/m |
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42.05.01.02d Agardite-(Ca)! CaCu6(AsO4)3(OH)6•3(H2O) 6/m |
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42.05.01.02e Agardite-(Ce)! (Ce,Ca)Cu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
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42.05.01.03 Goudeyite (Al,Y)Cu6(AsO4)3(OH)6•3(H2O) Unk Hex |
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42.05.01.04 Zalesiite! (Ca,Y)Cu6[(AsO4)2(AsO3OH)(OH)6]•3(H2O) P 63/m 6/m |
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42.05.01.06 Plumboagardite! (Pb,REE,Ca)Cu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
Strunz Class: |
08.DL.15 08 - PHOSPHATES, ARSENATES, VANADATES |
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08.D - Phosphates, etc |
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08.DL -With large and medium-sized cations, (OH, etc.):RO4 = 2:1 |
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08.DL.15 Agardite-(Dy)! (Dy,La,Ca)Cu6(AsO4)3(OH)6•3(H2O) 6/m |
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08.DL.15 Agardite-(Ca)! CaCu6(AsO4)3(OH)6•3(H2O) 6/m |
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08.DL.15 Agardite-(Ce)! (Ce,Ca)Cu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
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08.DL.15 Agardite-(La)! (La,Ca)Cu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
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08.DL.15 Agardite-(Nd)! (Pb,Nd,Y,La,Ca)Cu6(AsO4)3(OH)6•3(H2O) 6/m |
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08.DL.15 Agardite-(Y) (Y,Ca)Cu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
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08.DL.15 Goudeyite (Al,Y)Cu6(AsO4)3(OH)6•3(H2O) Unk Hex |
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08.DL.15 Zalesiite! (Ca,Y)Cu6[(AsO4)2(AsO3OH)(OH)6]•3(H2O) P 63/m 6/m |
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08.DL.15 Mixite BiCu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
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08.DL.15 Petersite-(Y) (Y,Ce,Nd,Ca)Cu6(PO4)3(OH)6•3(H2O) P 63/m 6/m |
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08.DL.15 Calciopetersite! CaCu6[(PO4)2(PO3OH)(OH)6]•3(H2O) P 63/m 6/m |
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08.DL.15 Plumboagardite! (Pb,REE,Ca)Cu6(AsO4)3(OH)6•3(H2O) P 63/m 6/m |
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Other Zalesiite Information
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References: |
NAME( AmMin, vol 85, p 1564) PHYS. PROP.(AmMin, vol 85, p 1564) OPTIC PROP.(AmMin, vol 85, p 1564) |
See Also: |
Links to other databases for Zalesiite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - GeoScienceWorld
4 - Google Images
5 - Google Scholar
6 - MinDAT
7 - Mineralienatlas (Deutsch)
8 - Online Mineral Museum
9 - QUT Mineral Atlas
10 - Ruff.Info
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Print or Cut-and-Paste your Zalesiite Specimen Label here :
Zalesiite
(Ca,Y)Cu6[(AsO4)2(AsO3OH)(OH)6]•3(H2O)
Dana No: 42.05.01.04 Strunz No: 08.DL.15
Locality:
Notes:
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