The Good Scents Company - Aromatic/Hydrocarbon/Inorganic Ingredients Catalog information

biphenyl
diphenyl

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  B0465 Biphenyl >99.5%(GC)
  SDS

Name: 1,1'-biphenyl CAS Number: 92-52-4 3D/inchi Other(deleted CASRN): 56481-93-7 ECHA EINECS - REACH Pre-Reg: 202-163-5 FDA UNII: 2L9GJK6MGN Nikkaji Web: J3.929B Beilstein Number: 1634058 MDL: MFCD00003054 CoE Number: 10978 XlogP3: 4.00 (est) Molecular Weight: 154.21170000 Formula: C12 H10 BioActivity Summary: listing NMR Predictor: Predict (works with chrome, Edge or firefox) EFSA/JECFA Comments: No longer supported by Industry (DG SANCO, 2012). Category:antioxidants and stabilizers US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search JECFA Food Flavoring: 1332 biphenyl JECFA Food Additive: Diphenyl GSFA Codex: Diphenyl (230) FEMA Number: 3129 diphenyl FDA: No longer provide for the use of these seven synthetic flavoring substances FDA Mainterm (SATF): 92-52-4 ; BIPHENYL FDA Regulation: FDA PART 178 -- INDIRECT FOOD ADDITIVES: ADJUVANTS, PRODUCTION AIDS, AND SANITIZERS Subpart C--Antioxidants and Stabilizers Sec. 178.2010 Antioxidants and/or stabilizers for polymers. Physical Properties: Appearance: white to pale amber yellow crystalline powder (est) Assay: 99.00 to 100.00 Food Chemicals Codex Listed: No Specific Gravity: 0.99200 @ 25.00 °C. Refractive Index: 1.47500 @ 20.00 °C. Melting Point: 69.00 °C. @ 760.00 mm Hg Boiling Point: 256.10 °C. @ 760.00 mm Hg Boiling Point: 160.00 to 161.00 °C. @ 50.00 mm Hg Vapor Pressure: 0.008930 mmHg @ 25.00 °C. Vapor Density: 5.31 ( Air = 1 ) Flash Point: > 212.00 °F. TCC ( > 100.00 °C. ) logP (o/w): 3.980 Soluble in:   alcohol   benzene   carbon disulfide   carbon tetrachloride   ether   methanol   water, 6.94 mg/L @ 25 °C (exp) Insoluble in:   water Organoleptic Properties: Odor Type: green pungent rose green geranium Odor Description:at 0.10 % in propylene glycol. pungent rose green geranium Flavor Type: floral neroli bergamot cinnamon natural Taste Description: neroli bergamot cinnamon natural Odor and/or flavor descriptions from others (if found). Cosmetic Information: Suppliers: Eastman Chemical Biphenyl sds Odor: characteristic Use: Applications for biphenyl process fluid include process media or solvents in many industries, including chemicals and petrochemicals EMD Millipore For experimental / research use only. Biphenyl sds Glentham Life Sciences Biphenyl Penta International BIPHENYL Santa Cruz Biotechnology For experimental / research use only. Biphenyl Sigma-Aldrich Biphenyl, ≥99% sds Odor: geranium; green Certified Food Grade Products Synerzine Biphenyl TCI AMERICA For experimental / research use only. Biphenyl >99.5%(GC) sds Safety Information: Preferred SDS: View European information : Most important hazard(s): Xi N - Irritant, Dangerous for the environment. R 36/37/38 - Irritating to eyes, respiratory system, and skin. R 50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S 02 - Keep out of the reach of children. S 23 - Do not breath vapour. S 60 - This material and its container must be disposed of as hazardous waste. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: oral-rat LD50 2140 mg/kg GASTROINTESTINAL: ALTERATION IN GASTRIC SECRETION BEHAVIORAL: MUSCLE WEAKNESS BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) National Technical Information Service. Vol. OTS0546109 oral-rabbit LD50 2400 mg/kg Nagoya Shiritsu Daigaku Igakkai Zasshi. Journal of the Nagoya City University Medical Association. Vol. 28, Pg. 983, 1977. oral-mouse LD50 1900 mg/kg BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" Shokuhin Eiseigaku Zasshi. Food Hygiene Journal. Vol. 24, Pg. 268, 1983. intravenous-mouse LD50 56 mg/kg U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00198 oral-cat LD50 > 2600 mg/kg "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A166, Pg. 1983 unreported-rat LD50 4500 mg/kg Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 53(5), Pg. 6, 1988. Dermal Toxicity: skin-rabbit LD50 > 5010 mg/kg Monsanto Co. Toxicity Information. Inhalation Toxicity: inhalation-rat LC50 > 200 mg/m3 Monsanto Co. Toxicity Information. inhalation-human TCLo 4400 ug/m3 GASTROINTESTINAL: NAUSEA OR VOMITING GASTROINTESTINAL: OTHER CHANGES PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) Archives of Environmental Health. Vol. 26, Pg. 70, 1973. Safety in Use Information: Category: antioxidants and stabilizers Recommendation for biphenyl usage levels up to:   not for fragrance use.   Maximised Survey-derived Daily Intakes (MSDI-EU): 0.00085 (μg/capita/day) Maximised Survey-derived Daily Intakes (MSDI-USA): 0.70 (μg/capita/day) Threshold of Concern: 90 (μg/person/day) Structure Class: III Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library publication number: 4 Click here to view publication 4   average usual ppm average maximum ppm baked goods: - 2.00000 beverages(nonalcoholic): - 2.00000 beverages(alcoholic): - - breakfast cereal: - - cheese: - - chewing gum: - - condiments / relishes: - - confectionery froastings: - - egg products: - - fats / oils: - - fish products: - - frozen dairy: - 2.00000 fruit ices: - 2.00000 gelatins / puddings: - 2.00000 granulated sugar: - - gravies: - - hard candy: - 2.00000 imitation dairy: - - instant coffee / tea: - - jams / jellies: - - meat products: - - milk products: - - nut products: - - other grains: - - poultry: - - processed fruits: - - processed vegetables: - - reconstituted vegetables: - - seasonings / flavors: - - snack foods: - - soft candy: - - soups: - - sugar substitutes: - - sweet sauces: - - Safety References: European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... European Food Safety Authority (EFSA) reference(s): Flavouring Group Evaluation 78 (FGE.78)[1] - Consideration of Aliphatic and alicyclic and aromatic hydrocarbons evaluated by JECFA (63rd meeting) structurally related to aliphatic and aromatic hydrocarbons evaluated by EFSA in FGE.25 - Scientific Opinion of the Panel on Food Additives,Flavourings, Processing Aids and Materials in Contact with Food (AFC) View page or View pdf Scientific Opinion on Flavouring Group Evaluation 78, Revision 1 (FGE.78Rev1): Consideration of aliphatic and alicyclic and aromatic hydrocarbons evaluated by JECFA (63rd meeting) structurally related to aliphatic and aromatic hydrocarbons evaluated by EFSA in FGE.25Rev2 View page or View pdf Scientific Opinion on Flavouring Group Evaluation 78, Revision 2 (FGE.78Rev2): Consideration of aliphatic and alicyclic and aromatic hydrocarbons evaluated by JECFA (63rd meeting) structurally related to aliphatic hydrocarbons evaluated by EFSA in FGE.25Rev3 View page or View pdf EPI System: View EPA-Iris:IRIS ClinicalTrials.gov:search NIOSH International Chemical Safety Cards:search NIOSH Pocket Guide:search Chemical Carcinogenesis Research Information System:Search AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search Carcinogenic Potency Database:Search EPA GENetic TOXicology:Search EPA Substance Registry Services (TSCA):92-52-4 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :7095 National Institute of Allergy and Infectious Diseases:Data WISER:UN 3077 WGK Germany:2 1,1'-biphenyl Chemidplus:0000092524 EPA/NOAA CAMEO:hazardous materials RTECS:92-52-4 References: Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements FDA Substances Added to Food (formerly EAFUS): View FDA Indirect Additives used in Food Contact Substances: View CHEBI: View CHEMBL: View Metabolomics Database: Search UM BBD: Search KEGG (GenomeNet): C06588 HMDB (The Human Metabolome Database): HMDB34437 FooDB: FDB012838 Export Tariff Code: 2902.90.6000 VCF-Online: VCF Volatile Compounds in Food ChemSpider: View Wikipedia: View Formulations/Preparations: •phph •xenene •lemonene •phenador-x •carolid al •bulk molten or flaked, technical grades (99.9% purity). monsanto co •95% and 99% molten or flake grades. sybron chemicals, inc •technical grade of 93-97% purity. high purity is greater than or equal to 99.9% purity. Potential Blenders and core components note For Odor alliaceous dibutyl sulfide FL/FR balsamic benzophenone FR ethereal ethyl formate FL/FR floral laevo- citronellol FL/FR citronellyl acetate FL/FR (E)- citronellyl tiglate FL/FR cyclohexyl propanol FR gamma- damascone FR dihydrorose oxide FR dimethyl benzyl carbinol FL/FR floral pyran FR geranium dihydropyran FR geranium nitrile FR geranium oil africa FL/FR geranium oil egypt FL/FR geranium pyran FR geranyl formate FL/FR geranyl hexanoate FL/FR geranyl nonanoate CS geranyl tiglate FL/FR methyl citronellate FL/FR muguet carbinol FL/FR musk acetate FR narcissus acetate FL/FR peony acetonitrile FR phenethyl formate FL/FR phenethyl pivalate FL/FR phenyl acetaldehyde digeranyl acetal FR phenyl propyl phenyl acetate FR rhodinyl propionate FL/FR (Z)- rose oxide FL/FR laevo- rose oxide FL/FR rose pyran FR fruity citronellyl isobutyrate FL/FR green diphenyl methane FL/FR diphenyl oxide FL/FR geranium absolute FL/FR geranium thiazole FL/FR (Z)-3- hexen-1-yl phenyl acetate FL/FR phenethyl isopropyl ether FR phenethyl oxyacetaldehyde FR phenethyl tiglate FL/FR herbal geranium cyclohexane FR leathery leather cyclohexanol FR woody (E)- ethyl geranate FR For Flavor balsamic phenethyl pivalate FL/FR ethereal ethyl formate FL/FR floral laevo- citronellol FL/FR citronellyl acetate FL/FR geranium oil africa FL/FR geranium oil egypt FL/FR geranyl tiglate FL/FR methyl citronellate FL/FR muguet carbinol FL/FR laevo- rose oxide FL/FR fruity citronellyl isobutyrate FL/FR geranyl hexanoate FL/FR rhodinyl propionate FL/FR green (E)- citronellyl tiglate FL/FR dibutyl sulfide FL/FR diphenyl methane FL/FR diphenyl oxide FL/FR geranium absolute FL/FR geranium thiazole FL/FR geranyl formate FL/FR (Z)-3- hexen-1-yl phenyl acetate FL/FR narcissus acetate FL/FR phenethyl formate FL/FR phenethyl tiglate FL/FR (Z)- rose oxide FL/FR medicinal dimethyl benzyl carbinol FL/FR Potential Uses: Occurrence (nature, food, other):note   carrot root Search Trop Picture   coal tar Search PMC Picture   corn silk Search Trop Picture   lovage root Search Trop Picture   potato Search Trop Picture   tomato Search Trop Picture Synonyms:   bibenzene   bifenyl 1,1'- biphenyl   blinin   carolid AL   diphenyl 1,1'- diphenyl   dowtherm   fenbufen Imp. C (EP)   lemonene   phenador-x   phenyl benzene   phenylbenzene   tetrosin LY   xenene Articles:

Notes: Fungistat, esp. for citrus fruits. Used as food preservative and flavouring agent. Detected in bilberry, wine grape, carrot, peas, rum, potato, bell pepper, tomato, butter, milk, smoked fatty fish, cocoa, coffee, roast peanuts, olive, buckwheat and tamarind. Generally, the fruit packaging is impregnated with biphenyl, which evaporates into the air space surrounding the fruit. Some biphenyl is absorbed by the fruit skins