Rhodium(I)-catalyzed N–CN bond cleavage: intramolecular β-cyanation of styrenes
- ️John R. Falck
Abstract
We report herein the first example of intramolecular cyanation of a styrene by a rhodium(I)-catalyzed N–CN cleavage reaction. Substituents on the arenes or the styrene alpha-position are tolerated. Our results demonstrate that alkene cyanation can indeed be atom economical.
Supplementary files
Article information
- https://doi.org/10.1039/C3CC43597K
- Communication
- 14 May 2013
- 28 May 2013
- 30 May 2013
DOI
Article type
Submitted
Accepted
First published
Chem. Commun., 2013,49, 6516-6518
Permissions
Rhodium(I)-catalyzed N–CN bond cleavage: intramolecular β-cyanation of styrenes
R. Wang and J. R. Falck, Chem. Commun., 2013, 49, 6516 DOI: 10.1039/C3CC43597K
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