Eclipsed conformation, the Glossary
In chemistry an eclipsed conformation is a conformation in which two substituents X and Y on adjacent atoms A, B are in closest proximity, implying that the torsion angle X–A–B–Y is 0°.[1]
Table of Contents
25 relations: Activation energy, Butane, Chemical bond, Chemistry, Computational chemistry, Conformational isomerism, Dihedral angle, Electron diffraction, Ethane, Gauche effect, Hyperconjugation, Inorganic Syntheses, Microwave spectroscopy, Molecular mechanics, Newman projection, Nuclear magnetic resonance spectroscopy, Orbital hybridisation, Potassium octachlorodimolybdate, Quadruple bond, Sigma bond, Staggered conformation, Steric effects, Substituent, Tetramethylbutane, X-ray crystallography.
Activation energy
In the Arrhenius model of reaction rates, activation energy is the minimum amount of energy that must be available to reactants for a chemical reaction to occur.
See Eclipsed conformation and Activation energy
Butane
Butane or n-butane is an alkane with the formula C4H10.
See Eclipsed conformation and Butane
Chemical bond
A chemical bond is the association of atoms or ions to form molecules, crystals, and other structures.
See Eclipsed conformation and Chemical bond
Chemistry
Chemistry is the scientific study of the properties and behavior of matter.
See Eclipsed conformation and Chemistry
Computational chemistry
Computational chemistry is a branch of chemistry that uses computer simulations to assist in solving chemical problems.
See Eclipsed conformation and Computational chemistry
Conformational isomerism
In chemistry, conformational isomerism is a form of stereoisomerism in which the isomers can be interconverted just by rotations about formally single bonds (refer to figure on single bond rotation). Eclipsed conformation and conformational isomerism are Stereochemistry.
See Eclipsed conformation and Conformational isomerism
Dihedral angle
A dihedral angle is the angle between two intersecting planes or half-planes. Eclipsed conformation and dihedral angle are Stereochemistry.
See Eclipsed conformation and Dihedral angle
Electron diffraction
Electron diffraction is a generic term for phenomena associated with changes in the direction of electron beams due to elastic interactions with atoms.
See Eclipsed conformation and Electron diffraction
Ethane
Ethane is a naturally occurring organic chemical compound with chemical formula.
See Eclipsed conformation and Ethane
Gauche effect
In the study of conformational isomerism, the gauche effect is an atypical situation where a gauche conformation (groups separated by a torsion angle of approximately 60°) is more stable than the anti conformation (180°). Eclipsed conformation and gauche effect are Stereochemistry.
See Eclipsed conformation and Gauche effect
Hyperconjugation
In organic chemistry, hyperconjugation (σ-conjugation or no-bond resonance) refers to the delocalization of electrons with the participation of bonds of primarily σ-character.
See Eclipsed conformation and Hyperconjugation
Inorganic Syntheses
Inorganic Syntheses is a book series which aims to publish "detailed and foolproof" procedures for the synthesis of inorganic compounds.
See Eclipsed conformation and Inorganic Syntheses
Microwave spectroscopy
Microwave spectroscopy is the spectroscopy method that employs microwaves, i.e. electromagnetic radiation at GHz frequencies, for the study of matter.
See Eclipsed conformation and Microwave spectroscopy
Molecular mechanics
Molecular mechanics uses classical mechanics to model molecular systems.
See Eclipsed conformation and Molecular mechanics
Newman projection
A Newman projection is a drawing that helps visualize the 3-dimensional structure of a molecule. Eclipsed conformation and Newman projection are Stereochemistry.
See Eclipsed conformation and Newman projection
Nuclear magnetic resonance spectroscopy
Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique based on re-orientation of atomic nuclei with non-zero nuclear spins in an external magnetic field.
See Eclipsed conformation and Nuclear magnetic resonance spectroscopy
Orbital hybridisation
In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals to form new hybrid orbitals (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory. Eclipsed conformation and orbital hybridisation are Stereochemistry.
See Eclipsed conformation and Orbital hybridisation
Potassium octachlorodimolybdate
Potassium octachlorodimolybdate (systematically named potassium bis(tetrachloromolybdate)(Mo–Mo)(4−)) is an inorganic compound with the chemical formula.
See Eclipsed conformation and Potassium octachlorodimolybdate
Quadruple bond
A quadruple bond is a type of chemical bond between two atoms involving eight electrons.
See Eclipsed conformation and Quadruple bond
Sigma bond
In chemistry, sigma bonds (σ bonds) are the strongest type of covalent chemical bond.
See Eclipsed conformation and Sigma bond
Staggered conformation
In organic chemistry, a staggered conformation is a chemical conformation of an ethane-like moiety abcX–Ydef in which the substituents a, b, and c are at the maximum distance from d, e, and f; this requires the torsion angles to be 60°. Eclipsed conformation and staggered conformation are Stereochemistry.
See Eclipsed conformation and Staggered conformation
Steric effects
Steric effects arise from the spatial arrangement of atoms. Eclipsed conformation and Steric effects are Stereochemistry.
See Eclipsed conformation and Steric effects
Substituent
In organic chemistry, a substituent is one or a group of atoms that replaces (one or more) atoms, thereby becoming a moiety in the resultant (new) molecule.
See Eclipsed conformation and Substituent
Tetramethylbutane
Tetramethylbutane, sometimes called hexamethylethane, is a hydrocarbon with formula C8H18 or (H3C-)3C-C(-CH3)3.
See Eclipsed conformation and Tetramethylbutane
X-ray crystallography
X-ray crystallography is the experimental science of determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract in specific directions.
See Eclipsed conformation and X-ray crystallography
References
[1] https://en.wikipedia.org/wiki/Eclipsed_conformation
Also known as Eclipsed, Eclipsed form, Eclipsing strain.