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Hot band, the Glossary

Index Hot band

In molecular vibrational spectroscopy, a hot band is a band centred on a hot transition, which is a transition between two excited vibrational states, i.e. neither is the overall ground state.[1]

Table of Contents

  1. 15 relations: Allyn & Bacon, Boltzmann constant, Boltzmann distribution, Excited state, Ground state, Harmonic oscillator, Infrared spectroscopy, Molecular vibration, Normal mode, Overtone, Quantum harmonic oscillator, Quantum number, Raman spectroscopy, Redshift, Selection rule.

  2. Vibrational spectroscopy

Allyn & Bacon

Allyn & Bacon, founded in 1868, is a higher education textbook publisher in the areas of education, humanities and social sciences.

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Boltzmann constant

The Boltzmann constant is the proportionality factor that relates the average relative thermal energy of particles in a gas with the thermodynamic temperature of the gas.

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Boltzmann distribution

In statistical mechanics and mathematics, a Boltzmann distribution (also called Gibbs distribution Translated by J.B. Sykes and M.J. Kearsley. See section 28) is a probability distribution or probability measure that gives the probability that a system will be in a certain state as a function of that state's energy and the temperature of the system.

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Excited state

In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum).

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Ground state

The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system.

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Harmonic oscillator

In classical mechanics, a harmonic oscillator is a system that, when displaced from its equilibrium position, experiences a restoring force F proportional to the displacement x: \vec F.

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Infrared spectroscopy

Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. Hot band and infrared spectroscopy are vibrational spectroscopy.

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Molecular vibration

A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged.

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Normal mode

A normal mode of a dynamical system is a pattern of motion in which all parts of the system move sinusoidally with the same frequency and with a fixed phase relation.

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Overtone

An overtone is any resonant frequency above the fundamental frequency of a sound.

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Quantum harmonic oscillator

The quantum harmonic oscillator is the quantum-mechanical analog of the classical harmonic oscillator.

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Quantum number

In quantum physics and chemistry, quantum numbers are quantities that characterize the possible states of the system.

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Raman spectroscopy

Raman spectroscopy (named after physicist C. V. Raman) is a spectroscopic technique typically used to determine vibrational modes of molecules, although rotational and other low-frequency modes of systems may also be observed. Hot band and Raman spectroscopy are vibrational spectroscopy.

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Redshift

In physics, a redshift is an increase in the wavelength, and corresponding decrease in the frequency and photon energy, of electromagnetic radiation (such as light).

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Selection rule

In physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another.

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See also

Vibrational spectroscopy

References

[1] https://en.wikipedia.org/wiki/Hot_band

Also known as Difference transition, Hot transition.