Oxymercuration reaction, the Glossary
In organic chemistry, the oxymercuration reaction is an electrophilic addition reaction that transforms an alkene into a neutral alcohol.[1]
Table of Contents
28 relations: Acetal, Alcohol (chemistry), Alkene, Alkyne, Aqueous solution, Carbocation, Cis–trans isomerism, Claisen rearrangement, Cyclohexane conformation, Double bond, Electrophile, Electrophilic addition, Enol ether, Hydroboration–oxidation reaction, Hydroxy group, Lewis acids and bases, Markovnikov's rule, Mercury(II) acetate, Mukaiyama hydration, Nucleophile, Onium ion, Organic chemistry, Organic redox reaction, Organomercury chemistry, Resonance (chemistry), Sodium borohydride, Syn and anti addition, Tertiary carbon.
- Carbon-heteroatom bond forming reactions
Acetal
In organic chemistry, an acetal is a functional group with the connectivity.
See Oxymercuration reaction and Acetal
Alcohol (chemistry)
In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl functional group bound to carbon.
See Oxymercuration reaction and Alcohol (chemistry)
Alkene
In organic chemistry, an alkene, or olefin, is a hydrocarbon containing a carbon–carbon double bond.
See Oxymercuration reaction and Alkene
Alkyne
\ce \ce Acetylene \ce \ce \ce Propyne \ce \ce \ce \ce 1-Butyne In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond.
See Oxymercuration reaction and Alkyne
Aqueous solution
An aqueous solution is a solution in which the solvent is water.
See Oxymercuration reaction and Aqueous solution
Carbocation
A carbocation is an ion with a positively charged carbon atom.
See Oxymercuration reaction and Carbocation
Cis–trans isomerism
Cis–trans isomerism, also known as geometric isomerism, describes certain arrangements of atoms within molecules.
See Oxymercuration reaction and Cis–trans isomerism
Claisen rearrangement
The Claisen rearrangement is a powerful carbon–carbon bond-forming chemical reaction discovered by Rainer Ludwig Claisen.
See Oxymercuration reaction and Claisen rearrangement
Cyclohexane conformation
Cyclohexane conformations are any of several three-dimensional shapes adopted by molecules of cyclohexane.
See Oxymercuration reaction and Cyclohexane conformation
Double bond
In chemistry, a double bond is a covalent bond between two atoms involving four bonding electrons as opposed to two in a single bond.
See Oxymercuration reaction and Double bond
Electrophile
In chemistry, an electrophile is a chemical species that forms bonds with nucleophiles by accepting an electron pair.
See Oxymercuration reaction and Electrophile
Electrophilic addition
In organic chemistry, an electrophilic addition (AE) reaction is an addition reaction where a chemical compound containing a double or triple bond has a π bond broken, with the formation of two new σ bonds.
See Oxymercuration reaction and Electrophilic addition
Enol ether
In organic chemistry an enol ether is an alkene with an alkoxy substituent.
See Oxymercuration reaction and Enol ether
Hydroboration–oxidation reaction
Hydroboration–oxidation reaction is a two-step hydration reaction that converts an alkene into an alcohol. Oxymercuration reaction and Hydroboration–oxidation reaction are addition reactions.
See Oxymercuration reaction and Hydroboration–oxidation reaction
Hydroxy group
In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom.
See Oxymercuration reaction and Hydroxy group
Lewis acids and bases
A Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct.
See Oxymercuration reaction and Lewis acids and bases
Markovnikov's rule
In organic chemistry, Markovnikov's rule or Markownikoff's rule describes the outcome of some addition reactions.
See Oxymercuration reaction and Markovnikov's rule
Mercury(II) acetate
Mercury(II) acetate, also known as mercuric acetate is a chemical compound, the mercury(II) salt of acetic acid, with the formula Hg(O2CCH3)2.
See Oxymercuration reaction and Mercury(II) acetate
Mukaiyama hydration
The Mukaiyama hydration is an organic reaction involving formal addition of an equivalent of water across an olefin by the action of catalytic bis(acetylacetonato)cobalt(II) complex, phenylsilane and atmospheric oxygen to produce an alcohol with Markovnikov selectivity. Oxymercuration reaction and Mukaiyama hydration are addition reactions and carbon-heteroatom bond forming reactions.
See Oxymercuration reaction and Mukaiyama hydration
Nucleophile
In chemistry, a nucleophile is a chemical species that forms bonds by donating an electron pair.
See Oxymercuration reaction and Nucleophile
Onium ion
In chemistry, an onium ion is a cation formally obtained by the protonation of mononuclear parent hydride of a pnictogen (group 15 of the periodic table), chalcogen (group 16), or halogen (group 17).
See Oxymercuration reaction and Onium ion
Organic chemistry
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.
See Oxymercuration reaction and Organic chemistry
Organic redox reaction
Organic reductions or organic oxidations or organic redox reactions are redox reactions that take place with organic compounds.
See Oxymercuration reaction and Organic redox reaction
Organomercury chemistry
Organomercury chemistry refers to the study of organometallic compounds that contain mercury.
See Oxymercuration reaction and Organomercury chemistry
Resonance (chemistry)
In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.
See Oxymercuration reaction and Resonance (chemistry)
Sodium borohydride
Sodium borohydride, also known as sodium tetrahydridoborate and sodium tetrahydroborate, is an inorganic compound with the formula (sometimes written as). It is a white crystalline solid, usually encountered as an aqueous basic solution.
See Oxymercuration reaction and Sodium borohydride
Syn and anti addition
In organic chemistry, syn- and anti-addition are different ways in which substituent molecules can be added to an alkene or alkyne. Oxymercuration reaction and syn and anti addition are addition reactions.
See Oxymercuration reaction and Syn and anti addition
Tertiary carbon
A tertiary carbon atom is a carbon atom bound to three other carbon atoms.
See Oxymercuration reaction and Tertiary carbon
See also
Carbon-heteroatom bond forming reactions
- Azo coupling
- Bartoli indole synthesis
- Boudouard reaction
- Cadogan–Sundberg indole synthesis
- Diazonium compound
- Grignard reagent
- Haloform reaction
- Hegedus indole synthesis
- Hurd–Mori 1,2,3-thiadiazole synthesis
- Kharasch–Sosnovsky reaction
- Knorr pyrrole synthesis
- Leimgruber–Batcho indole synthesis
- Mukaiyama hydration
- Nenitzescu indole synthesis
- Oxymercuration reaction
- Reed reaction
- Schotten–Baumann reaction
- Ullmann condensation
- Williamson ether synthesis
- Yamaguchi esterification
References
[1] https://en.wikipedia.org/wiki/Oxymercuration_reaction
Also known as Demercuration, Oxymercuration, Oxymercuration-demercuration, Oxymercuration-demercuration reaction, Oxymercuration-reduction, Oxymercuration-reduction reaction.