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CN103478151A - Pesticide composition containing spirotetramat - Google Patents

  • ️Wed Jan 01 2014

CN103478151A - Pesticide composition containing spirotetramat - Google Patents

Pesticide composition containing spirotetramat Download PDF

Info

Publication number
CN103478151A
CN103478151A CN201310422203.5A CN201310422203A CN103478151A CN 103478151 A CN103478151 A CN 103478151A CN 201310422203 A CN201310422203 A CN 201310422203A CN 103478151 A CN103478151 A CN 103478151A Authority
CN
China
Prior art keywords
agent
ethyl ester
spiral shell
shell worm
worm ethyl
Prior art date
2013-09-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310422203.5A
Other languages
Chinese (zh)
Inventor
束兆林
缪康
赵来成
姚克兵
吉沐祥
杨红福
张玉军
陈建伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Lvdun Plant Protection Agrochemlcal Experimental Co Ltd
Original Assignee
Jiangsu Lvdun Plant Protection Agrochemlcal Experimental Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
2013-09-17
Filing date
2013-09-17
Publication date
2014-01-01
2013-09-17 Application filed by Jiangsu Lvdun Plant Protection Agrochemlcal Experimental Co Ltd filed Critical Jiangsu Lvdun Plant Protection Agrochemlcal Experimental Co Ltd
2013-09-17 Priority to CN201310422203.5A priority Critical patent/CN103478151A/en
2014-01-01 Publication of CN103478151A publication Critical patent/CN103478151A/en
Status Pending legal-status Critical Current

Links

  • 239000000203 mixture Substances 0.000 title claims abstract description 20
  • 239000000575 pesticide Substances 0.000 title abstract description 17
  • 239000005931 Spirotetramat Substances 0.000 title abstract description 5
  • CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 title abstract description 5
  • 239000004480 active ingredient Substances 0.000 claims abstract description 22
  • 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
  • 239000000375 suspending agent Substances 0.000 claims abstract description 18
  • 125000004494 ethyl ester group Chemical group 0.000 claims description 61
  • CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 claims description 40
  • 229940079888 nitenpyram Drugs 0.000 claims description 40
  • 239000002917 insecticide Substances 0.000 claims description 25
  • 239000000843 powder Substances 0.000 claims description 21
  • RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
  • 239000012752 auxiliary agent Substances 0.000 claims description 20
  • LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
  • 238000009736 wetting Methods 0.000 claims description 17
  • XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
  • 239000002270 dispersing agent Substances 0.000 claims description 14
  • WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 12
  • YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 12
  • KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
  • 239000000470 constituent Substances 0.000 claims description 12
  • YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 12
  • 230000000749 insecticidal effect Effects 0.000 claims description 11
  • -1 neopelex Chemical compound 0.000 claims description 10
  • 239000003002 pH adjusting agent Substances 0.000 claims description 10
  • 238000002360 preparation method Methods 0.000 claims description 10
  • 150000001875 compounds Chemical class 0.000 claims description 9
  • DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
  • 230000000740 bleeding effect Effects 0.000 claims description 8
  • 239000013530 defoamer Substances 0.000 claims description 8
  • 229910052708 sodium Inorganic materials 0.000 claims description 8
  • 239000011734 sodium Substances 0.000 claims description 8
  • 239000003381 stabilizer Substances 0.000 claims description 8
  • 239000002562 thickening agent Substances 0.000 claims description 8
  • QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
  • 239000005995 Aluminium silicate Substances 0.000 claims description 6
  • 239000002202 Polyethylene glycol Substances 0.000 claims description 6
  • VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
  • 239000002253 acid Substances 0.000 claims description 6
  • 239000003463 adsorbent Substances 0.000 claims description 6
  • 235000012211 aluminium silicate Nutrition 0.000 claims description 6
  • NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
  • 229920001223 polyethylene glycol Polymers 0.000 claims description 6
  • 229920002545 silicone oil Polymers 0.000 claims description 6
  • 239000000080 wetting agent Substances 0.000 claims description 6
  • 229920001285 xanthan gum Polymers 0.000 claims description 6
  • PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
  • NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
  • XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
  • 239000007859 condensation product Substances 0.000 claims description 4
  • RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 4
  • 235000019197 fats Nutrition 0.000 claims description 4
  • 229920001296 polysiloxane Polymers 0.000 claims description 4
  • 235000021003 saturated fats Nutrition 0.000 claims description 4
  • SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 claims description 4
  • 241000196324 Embryophyta Species 0.000 claims description 3
  • YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 claims description 2
  • CUFXMPWHOWYNSO-UHFFFAOYSA-N 2-[(4-methylphenoxy)methyl]oxirane Chemical compound C1=CC(C)=CC=C1OCC1OC1 CUFXMPWHOWYNSO-UHFFFAOYSA-N 0.000 claims description 2
  • AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 claims description 2
  • 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
  • NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims description 2
  • RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims description 2
  • BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 2
  • LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
  • 239000005770 Eugenol Substances 0.000 claims description 2
  • 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
  • 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
  • RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
  • 229910019142 PO4 Inorganic materials 0.000 claims description 2
  • FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 claims description 2
  • 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
  • UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims description 2
  • PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
  • 239000004283 Sodium sorbate Substances 0.000 claims description 2
  • 150000007513 acids Chemical class 0.000 claims description 2
  • 125000000217 alkyl group Chemical group 0.000 claims description 2
  • 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
  • 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
  • PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 2
  • 150000004056 anthraquinones Chemical class 0.000 claims description 2
  • 229960000892 attapulgite Drugs 0.000 claims description 2
  • 238000000498 ball milling Methods 0.000 claims description 2
  • 229920001400 block copolymer Polymers 0.000 claims description 2
  • 239000004202 carbamide Substances 0.000 claims description 2
  • 229920006184 cellulose methylcellulose Polymers 0.000 claims description 2
  • LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 2
  • 229960002217 eugenol Drugs 0.000 claims description 2
  • 235000011187 glycerol Nutrition 0.000 claims description 2
  • 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
  • YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 claims description 2
  • 229920005610 lignin Polymers 0.000 claims description 2
  • 239000000944 linseed oil Substances 0.000 claims description 2
  • 235000021388 linseed oil Nutrition 0.000 claims description 2
  • 229920000609 methyl cellulose Polymers 0.000 claims description 2
  • 239000001923 methylcellulose Substances 0.000 claims description 2
  • NALMPLUMOWIVJC-UHFFFAOYSA-N n,n,4-trimethylbenzeneamine oxide Chemical compound CC1=CC=C([N+](C)(C)[O-])C=C1 NALMPLUMOWIVJC-UHFFFAOYSA-N 0.000 claims description 2
  • WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 2
  • 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
  • 239000001301 oxygen Substances 0.000 claims description 2
  • 229910052760 oxygen Inorganic materials 0.000 claims description 2
  • 229910052625 palygorskite Inorganic materials 0.000 claims description 2
  • 239000002245 particle Substances 0.000 claims description 2
  • NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
  • 239000010452 phosphate Substances 0.000 claims description 2
  • 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
  • 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
  • 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 2
  • 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
  • 229940096992 potassium oleate Drugs 0.000 claims description 2
  • MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 claims description 2
  • ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
  • 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 claims description 2
  • QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 claims description 2
  • 229960003415 propylparaben Drugs 0.000 claims description 2
  • YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims description 2
  • WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
  • 239000004299 sodium benzoate Substances 0.000 claims description 2
  • 235000010234 sodium benzoate Nutrition 0.000 claims description 2
  • 229940032753 sodium iodate Drugs 0.000 claims description 2
  • 235000015281 sodium iodate Nutrition 0.000 claims description 2
  • 239000011697 sodium iodate Substances 0.000 claims description 2
  • LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 claims description 2
  • 235000019250 sodium sorbate Nutrition 0.000 claims description 2
  • 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
  • 235000011152 sodium sulphate Nutrition 0.000 claims description 2
  • 239000003549 soybean oil Substances 0.000 claims description 2
  • 235000012424 soybean oil Nutrition 0.000 claims description 2
  • BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
  • 150000003871 sulfonates Chemical class 0.000 claims description 2
  • RSNQKPMXXVDJFG-UHFFFAOYSA-N tetrasiloxane Chemical compound [SiH3]O[SiH2]O[SiH2]O[SiH3] RSNQKPMXXVDJFG-UHFFFAOYSA-N 0.000 claims description 2
  • ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 claims description 2
  • 230000000694 effects Effects 0.000 abstract description 10
  • 239000002131 composite material Substances 0.000 abstract description 8
  • 241000209094 Oryza Species 0.000 abstract description 7
  • 235000007164 Oryza sativa Nutrition 0.000 abstract description 7
  • 235000009566 rice Nutrition 0.000 abstract description 7
  • 230000002265 prevention Effects 0.000 abstract description 3
  • 241001124076 Aphididae Species 0.000 abstract description 2
  • 241000607479 Yersinia pestis Species 0.000 abstract description 2
  • 238000003912 environmental pollution Methods 0.000 abstract description 2
  • 239000000126 substance Substances 0.000 abstract description 2
  • 235000013311 vegetables Nutrition 0.000 abstract description 2
  • 241001466042 Fulgoromorpha Species 0.000 abstract 3
  • 238000012856 packing Methods 0.000 abstract 2
  • 241000254127 Bemisia tabaci Species 0.000 abstract 1
  • 206010059866 Drug resistance Diseases 0.000 abstract 1
  • YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 abstract 1
  • 230000005923 long-lasting effect Effects 0.000 abstract 1
  • 239000004563 wettable powder Substances 0.000 abstract 1
  • 241000176086 Sogatella furcifera Species 0.000 description 14
  • 239000003814 drug Substances 0.000 description 9
  • 241001556089 Nilaparvata lugens Species 0.000 description 8
  • 241000238631 Hexapoda Species 0.000 description 5
  • 238000012360 testing method Methods 0.000 description 4
  • 230000002045 lasting effect Effects 0.000 description 3
  • 239000005885 Buprofezin Substances 0.000 description 2
  • 241001498622 Cixius wagneri Species 0.000 description 2
  • 239000005906 Imidacloprid Substances 0.000 description 2
  • 241000819999 Nymphes Species 0.000 description 2
  • 241000700605 Viruses Species 0.000 description 2
  • 235000021329 brown rice Nutrition 0.000 description 2
  • PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 2
  • 238000002474 experimental method Methods 0.000 description 2
  • YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 2
  • 229940056881 imidacloprid Drugs 0.000 description 2
  • 238000012545 processing Methods 0.000 description 2
  • 238000005507 spraying Methods 0.000 description 2
  • MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
  • 235000000318 Bindesalat Nutrition 0.000 description 1
  • 244000106835 Bindesalat Species 0.000 description 1
  • 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
  • 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
  • 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
  • 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
  • 102000002322 Egg Proteins Human genes 0.000 description 1
  • 108010000912 Egg Proteins Proteins 0.000 description 1
  • 206010034133 Pathogen resistance Diseases 0.000 description 1
  • OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
  • 239000005925 Pymetrozine Substances 0.000 description 1
  • 241000194622 Tagosodes orizicolus Species 0.000 description 1
  • 241001414989 Thysanoptera Species 0.000 description 1
  • 238000010521 absorption reaction Methods 0.000 description 1
  • 239000003905 agrochemical Substances 0.000 description 1
  • 229930014345 anabasine Natural products 0.000 description 1
  • 230000004071 biological effect Effects 0.000 description 1
  • 239000003153 chemical reaction reagent Substances 0.000 description 1
  • 201000010099 disease Diseases 0.000 description 1
  • 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
  • 229940079593 drug Drugs 0.000 description 1
  • 235000013399 edible fruits Nutrition 0.000 description 1
  • 238000005516 engineering process Methods 0.000 description 1
  • 238000009472 formulation Methods 0.000 description 1
  • 230000036039 immunity Effects 0.000 description 1
  • 238000011835 investigation Methods 0.000 description 1
  • 230000009571 larval growth Effects 0.000 description 1
  • 230000007774 longterm Effects 0.000 description 1
  • 231100000053 low toxicity Toxicity 0.000 description 1
  • 238000004519 manufacturing process Methods 0.000 description 1
  • 238000000034 method Methods 0.000 description 1
  • PEQJBOMPGWYIRO-UHFFFAOYSA-N n-ethyl-3,4-dimethoxyaniline Chemical class CCNC1=CC=C(OC)C(OC)=C1 PEQJBOMPGWYIRO-UHFFFAOYSA-N 0.000 description 1
  • 210000004681 ovum Anatomy 0.000 description 1
  • 230000003449 preventive effect Effects 0.000 description 1
  • 239000000047 product Substances 0.000 description 1
  • QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 description 1
  • 238000011160 research Methods 0.000 description 1
  • 238000001228 spectrum Methods 0.000 description 1
  • 230000002195 synergetic effect Effects 0.000 description 1

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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a pesticide composite containing spirotetramat and belongs to the technical field of pest chemical prevention. The pesticide composite comprises active ingredients, namely A spirotetramat and B dinotefuran, wherein the weight ratio of A and B is 1:20-20:1. Besides the active ingredients, the pesticide composite further comprises auxiliaries and packing. The active ingredients, namely A and B occupy 15%-50% of the total weight of pesticides, the auxiliaries occupy 20%-30% of the total weight of the pesticides, and the rest is the packing. The pesticide composite can be prepared into wettable powder, suspending agents and the like. The pesticide composition containing the spirotetramat has good prevention effects on rice planthoppers, aphids, vegetable bemisia tabaci and the like. Compared with a conventional agent for preventing the rice planthoppers, the pesticide composite can reduce a dosage, reduce environmental pollution and residues of agricultural products, can delay drug resistance on a single pesticide of the rice planthoppers, and has the advantage of a long lasting period. Compared with the single pesticide, the pesticide composite can reduce cost.

Description

The insecticides that contains spiral shell worm ethyl ester

Technical field

The invention belongs to the Chemical Control of Harmful Insects technical field, relate to a kind of insecticides that contains spiral shell worm ethyl ester.

Background technology

Rice fulgorid is one of rice growing season primary pest, and reproduction speed is fast, causing harm property is large, and the lighter causes Rice Heading undesired, thousand kernel weight alleviates, when serious, complete stool is withered, causes the significantly underproduction of paddy rice, but also can cause stripe virus disease, black streak dwarf by transmitted virus.For a long time, the control of rice fulgorid mainly relies on Imidacloprid, Buprofezin, organic phosphor and built agent thereof, wherein high malicious organophosphorous pesticide bans use of, due to long-term single continuous use, brown planthopper, small brown rice planthopper have produced obvious pesticide resistance to Imidacloprid, control efficiency sharply descends, and Buprofezin starts to descend to the preventive effect of rice fulgorid, to paddy rice, produces and brings serious loss.In recent years, control rice fulgorid agricultural chemicals newly developed (as pymetrozine) appearance, continuous, unreasonable use on a large scale in production, certainly will affect the control effect of rice fulgorid, accelerate the drug-fast generation of rice fulgorid, therefore, research and develop the Recompounded pesticide kind of high-efficiency prevention and control brown planthopper, small brown rice planthopper, delay the pesticide resistance of insect.

Spiral shell worm ethyl ester (spirotetramat) is the tetronic acid compounds, and spiral shell worm ethyl ester has unique function Characteristics, is one of modern insecticide had so far two-way interior suction conductive performance.This compound can upwards move down in whole plant corpus, arrives at blade face and bark, thereby control reaches the corticole insect of fruit as on romaine lettuce and Chinese cabbage internal lobe.The interior absorption of this uniqueness can be protected newborn stem, leaf and root, prevents ovum and the larval growth of insect.Its another characteristics are that the lasting period is long, and the effective control that reaches 8 weeks can be provided.

Nitenpyram is a kind of anabasine insecticide, has unique chemistry and biological property.For crops such as paddy rice, vegetables, various aphids, aleyrodid, rice-leaf hopper and thrips have been shown to remarkable activity, there is efficient, low toxicity, interior suction and without the large advantage of cross resistance four, and insecticidal spectrum is wider, the lasting period is longer, use safety.

At present, spiral shell worm ethyl ester, Nitenpyram separately higher for the cost of effectively controlling rice fulgorid, easily develop immunity to drugs, utilize the insecticide of different mechanism to carry out composite, be the main method of administering resistant insect.

Summary of the invention

Technical problem to be solved by this invention is to provide the insecticides that contains spiral shell worm ethyl ester that a kind of control efficiency is prevented and treated rice fulgorid preferably.

The insecticides that contains spiral shell worm ethyl ester of the present invention, its active ingredient: A is that spiral shell worm ethyl ester, B are Nitenpyram, wherein the weight ratio of effective constituents A and B is 1:20-20:1.

The insecticides that contains spiral shell worm ethyl ester of the present invention, except active ingredient, also include auxiliary agent and carrier, and wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, and auxiliary agent accounts for the 10%-30% of insecticidal total weight, and all the other are carrier.

The insecticides that contains spiral shell worm ethyl ester of the present invention can be prepared into the formulations such as wetting powder or suspending agent.

The wetting powder of the insecticides that the present invention contains spiral shell worm ethyl ester, wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, also include auxiliary agent and carrier in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are wetting agent 3-20%, dispersant 3-20%, adsorbent 2-20%; Surplus is carrier.

The wetting powder of the above-mentioned insecticides that contains spiral shell worm ethyl ester, preferred wherein effective constituents A and B account for the 15%-21% of insecticidal total weight, also include auxiliary agent and carrier in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are wetting agent 2%, dispersant 3%, adsorbent 2-10%; Surplus is carrier.

Wetting agent described in above-mentioned wetting powder is one or more in spaonin powder, sodium lignin sulfonate, neopelex;

Described dispersant is sodium metnylene bis-naphthalene sulfonate (being called for short NNO);

Described adsorbent is white carbon;

Described carrier is one or more in kaolin, attapulgite.

The suspending agent of the insecticides that the present invention contains spiral shell worm ethyl ester, wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, also include auxiliary agent and water in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are dispersant 2-30%, thickener 0.5-20%, stabilizing agent 0.01-20%, defoamer 1-5%, bleeding agent 1-5%, antifreezing agent 0.1-15%, appropriate pH adjusting agent, and the surplus water supplies 100%.

The suspending agent of the above-mentioned insecticides that contains spiral shell worm ethyl ester, preferably by weight wherein effective constituents A and B be 15-16%, also include auxiliary agent and water in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are dispersant 10%, thickener 1%, stabilizing agent 2%, defoamer 1%, bleeding agent 1-2%, antifreezing agent 12%, and pH adjusting agent is appropriate, and the surplus water supplies 100%.

Wherein said dispersant is selected from sodium lignin sulfonate, the lignin sodium iodate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, Fluhyzon formaldehyde condensation products sodium sulfonate, neopelex, lauryl sodium sulfate, potassium oleate, enuatrol, alkyl polyoxyethylene ether sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, alkylphenol-polyethenoxy base ether, Nonyl pheno base ether, polyoxyethylene polyoxypropylene base ether block copolymers, pull open powder, poly-second carboxylic esters sodium salt, one or more in alkylpolyoxyethylene phosphate or Fluhyzon first condensate sulfonates.

Wherein said thickener is selected from one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose or polyvinyl alcohol.

Wherein said stabilizing agent is selected from one or more in catechol, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, chloropropylene oxide, sodium sorbate, Sodium Benzoate, epoxidised soybean oil, linseed oil, quinhydrones, anthraquinone, eugenol, citric acid, hydroxy benzoate or nipasol.

Wherein said defoamer is chosen one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10 fat alcohol compound or II-ethylhexanol; Wherein silicone compound as organosilicon etc., as described in C10-20 saturated fat acid compounds as hendecanoic acid, tridecanoic acid, pentadecanoic acid etc., the C8-10 fat alcohol compound is as certain herbaceous plants with big flowers alcohol, ten alkanoic acids etc.

Wherein said antifreezing agent is selected from one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, sorbierite or urea.

Wherein said pH adjusting agent is selected from hydrogen-oxygen for one or more in sodium, ammoniacal liquor, acetic acid, citric acid or phosphoric acid; The consumption of pH adjusting agent is that to make the pH value of suspending agent be 5～9.

Wherein said bleeding agent is organosilicon, be selected from trisiloxanes, tetrasiloxane, many siloxanes one or more.

A kind of preparation method who contains spiral shell worm ethyl ester insecticides suspending agent for preparing, spiral shell worm ethyl ester, Nitenpyram are mixed in above-mentioned ratio with dispersant, thickener, stabilizing agent, defoamer, antifreezing agent, bleeding agent, pH adjusting agent and water, in ball mill, ball milling is 2～3 hours, makes particle diameter all below the 5 μ m.

Composite insecticide of the present invention is compared with conventional control rice fulgorid medicament, has the following advantages: 1, with single dose, compare said composition rice fulgorid is had to obvious synergistic effect, can significantly improve control efficiency; 2, reduce dosage, reduce the residual of environmental pollution and agricultural product; 3, can delay the pesticide resistance of rice fulgorid to single insecticide, 4, have advantages of that the lasting period is long, with single medicament, compare, can reduce costs.

Embodiment

Following examples are preferred condition, but active component of the present invention and proportioning, auxiliary element etc. are not limited to following examples, and in embodiment, all ratio by weight.

embodiment 1:

Prepare 15% Nitenpyram spiral shell worm ethyl ester wetting powder, each composition weight proportion and the percentage respectively accounted for are:

Nitenpyram (active ingredient) 5g (5%)

Spiral shell worm ethyl ester (active ingredient) 10g (10%)

Neopelex 2g (2%)

Sodium metnylene bis-naphthalene sulfonate (NNO) 3g (3%)

White carbon 5g (5%)

Sodium lignin sulfonate 5g (5%)

Kaolin is supplied 100g

embodiment 2:

Prepare 15% Nitenpyram spiral shell worm ethyl ester suspending agent, each composition weight proportion and the percentage respectively accounted for are:

Nitenpyram (active ingredient) 10g (10%)

Spiral shell worm ethyl ester (active ingredient) 5g (5%)

Sodium lignin sulfonate 10g (10%)

Ethylene glycol 12g (12%)

Xanthans 1g (1%)

Catechol 2 g (2%)

Silicone oil 1g (1%)

Organosilicon 1g (1%)

Water is supplied 100g

embodiment 3:

Prepare 15% Nitenpyram spiral shell worm ethyl ester suspending agent, each composition weight proportion and the percentage respectively accounted for are:

Nitenpyram (active ingredient) 10g (10%)

Spiral shell worm ethyl ester (active ingredient) 5g (5%)

Sodium lignin sulfonate 10g (10%)

Ethylene glycol 12g (12%)

Xanthans 1g (1%)

Catechol 2 g (2%)

Silicone oil 1g (1%)

Organosilicon 2g (2%)

Water is supplied 100g

embodiment 4:

Prepare 16% Nitenpyram spiral shell worm ethyl ester wetting powder, each composition weight proportion and the percentage respectively accounted for are:

Nitenpyram (active ingredient) 8g (8%)

Spiral shell worm ethyl ester (active ingredient) 8g (8%)

Neopelex 2g (2%)

NNO 3g （3%）

White carbon 5g (3%)

Sodium lignin sulfonate 5g (5%)

Kaolin is supplied 100 g

embodiment 5:

Prepare 21% Nitenpyram spiral shell worm ethyl ester wetting powder, each composition weight proportion and the percentage respectively accounted for are:

Nitenpyram (active ingredient) 20g (20%)

Spiral shell worm ethyl ester (active ingredient) 1g (1%)

Neopelex 2g (2%)

NNO 3g （3%）

White carbon 10g (10%)

Sodium lignin sulfonate 10g (5%)

Kaolin is supplied 100 g

embodiment 6:

Prepare 21% Nitenpyram spiral shell worm ethyl ester wetting powder, each composition weight proportion and the percentage respectively accounted for are:

Nitenpyram (active ingredient) 1g (1%)

Spiral shell worm ethyl ester (active ingredient) 20g (20%)

Neopelex 2g (2%)

Sodium metnylene bis-naphthalene sulfonate (NNO) 3g (3%)

White carbon 2g (2%)

Sodium lignin sulfonate 5g (5%)

Kaolin is supplied 100 g

embodiment 7:

Prepare 16% Nitenpyram spiral shell worm ethyl ester suspending agent, each composition weight proportion and the percentage respectively accounted for are:

Nitenpyram (active ingredient) 15g (15%)

Spiral shell worm ethyl ester (active ingredient) 1g (1%)

Sodium lignin sulfonate 10g (10%)

Ethylene glycol 12g (12%)

Xanthans 1g (1%)

Catechol 2 g (2%)

Silicone oil 1g (1%)

Organosilicon 2g (2%)

Water is supplied 100 g

embodiment 8:

Prepare 17% Nitenpyram spiral shell worm ethyl ester suspending agent, each composition weight proportion and the percentage respectively accounted for are:

Nitenpyram (active ingredient) 16g (16%)

Spiral shell worm ethyl ester (active ingredient) 1g (1%)

Sodium lignin sulfonate 10g (10%)

Ethylene glycol 12g (12%)

Xanthans 1g (1%)

Catechol 2 g (2%)

Silicone oil 1g (1%)

Organosilicon 1g (1%)

Water is supplied 100 g

effect experiment one:

Effect to embodiment tri-control white-backed planthoppers is carried out field control effectiveness test (in Table 1), test is processed: 15% Nitenpyram spiral shell worm ethyl ester suspending agent (embodiment tri-) mu consumption 10 grams, 25% Nitenpyram WP mu consumption 4 grams, 20% spiral shell worm ethyl ester wetting powder mu consumption 7 grams, in late July white-backed planthopper nymph peak period dispenser, 50 kilograms of every mu of water consumptions, even spraying, 150 square metres of every processing.Result of the test shows, after medicine 1 day, the control efficiency of 15% Nitenpyram spiral shell worm ethyl ester suspending agent mu consumption 10 grams all extremely significantly is better than the control efficiency of 20% spiral shell worm ethyl ester SC mu consumption 7 grams, with the control efficiency there was no significant difference of 25% Nitenpyram WP mu consumption 4 grams; After medicine 3 days, the control efficiency of 15% Nitenpyram spiral shell worm ethyl ester suspending agent mu consumption 10 grams all extremely significantly is better than, the control efficiency of 25% Nitenpyram WP mu consumption 4 grams and 20% spiral shell worm ethyl ester SC mu consumption 7 grams, after medicine 7 days, the control efficiency of 15% Nitenpyram spiral shell worm ethyl ester suspending agent mu consumption 10 grams reaches 97.15%, extremely significantly is better than, the control efficiency of 25% Nitenpyram WP mu consumption 4 grams, 20% spiral shell worm ethyl ester WG mu consumption 7 grams.

the control efficiency of table 1 15% Nitenpyram spiral shell worm ethyl ester suspending agent Whitebacked Planthopper

Figure 2013104222035100002DEST_PATH_IMAGE002

effect experiment two:

Effect to embodiment tetra-control brown planthopper adults is carried out field control effectiveness test (in Table 2), supply the reagent kind: 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 8 grams, 10 grams, 12 grams, 25% Nitenpyram WP mu consumption 4 grams, 24% spiral shell worm ethyl ester SC mu consumption 7 grams, in early September brown planthopper nymph peak period dispenser, 50 kilograms of every mu of water consumptions, even spraying, 20 square metres of every processing, triplicate.The field investigation result shows, after medicine 3 days, the control efficiency of 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 8 grams, 10 grams, 12 grams is respectively 84.56%, 94.34%, 97.22%, control effect and 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 8 grams, 10 grams and the 25% Nitenpyram WP mu consumption 4 gram there was no significant differences of 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 12 grams to brown planthopper wherein, significantly be better than the control efficiency of 24% spiral shell worm ethyl ester SC mu consumption 7 grams; 7-21 days 16% Nitenpyram spiral shell worm ethyl ester wetting powder mu consumption 8 grams after medicine, 10 grams, 12 grams all more than 90%, significantly are better than contrasting medicament 25% Nitenpyram WP mu consumption 4 grams, the 24% spiral shell worm ethyl ester SC control effect to brown planthopper to the control effect of brown planthopper.

the control efficiency of table 2 16 % Nitenpyram spiral shell worm ethyl ester wetting powders to brown planthopper

Figure 2013104222035100002DEST_PATH_IMAGE004

Claims (9)

1. the insecticides that contains spiral shell worm ethyl ester, is characterized in that its active ingredient: A is that spiral shell worm ethyl ester, B are Nitenpyram, and wherein the weight ratio of effective constituents A and B is 1:20-20:1.

2. the insecticides that contains spiral shell worm ethyl ester according to claim 1, is characterized in that also including auxiliary agent and carrier, and wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, and auxiliary agent accounts for the 10%-30% of insecticidal total weight, and all the other are carrier.

3. the insecticides that contains spiral shell worm ethyl ester according to claim 1, is characterized in that, for wetting powder, wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, also includes auxiliary agent and carrier in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are wetting agent 3-20%, dispersant 3-20%, adsorbent 2-20%; Surplus is carrier.

4. the insecticides that contains spiral shell worm ethyl ester according to claim 3, is characterized in that wherein effective constituents A and B account for the 15%-21% of insecticidal total weight, also include auxiliary agent and carrier in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are wetting agent 2%, dispersant 3%, adsorbent 2-10%; Surplus is carrier.

5. according to the described insecticides that contains spiral shell worm ethyl ester of claim 3 or 4, it is characterized in that the wetting agent of wetting powder wherein is one or more in spaonin powder, sodium lignin sulfonate, neopelex; Described dispersant is sodium metnylene bis-naphthalene sulfonate; Described adsorbent is white carbon; Described carrier is one or more in kaolin, attapulgite.

6. the insecticides that contains spiral shell worm ethyl ester according to claim 1, it is characterized in that suspending agent wherein wherein effective constituents A and B account for the 15%-50% of insecticidal total weight, also include auxiliary agent and water in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are dispersant 2-30%, thickener 0.5-20%, stabilizing agent 0.01-20%, defoamer 1-5%, bleeding agent 1-5%, antifreezing agent 0.1-15%, appropriate pH adjusting agent, and the surplus water supplies 100%.

7. the insecticides that contains spiral shell worm ethyl ester according to claim 6, is characterized in that wherein effective constituents A and B are 15-16%, also includes auxiliary agent and water in its composition; Described auxiliary agent and the weight ratio that respectively accounts for preparation thereof are dispersant 10%, thickener 1%, stabilizing agent 2%, defoamer 1%, bleeding agent 1-2%, antifreezing agent 12%, and pH adjusting agent is appropriate, and the surplus water supplies 100%.

8. according to the described insecticides that contains spiral shell worm ethyl ester of claim 6 or 7, it is characterized in that wherein said dispersant is selected from sodium lignin sulfonate, the lignin sodium iodate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, Fluhyzon formaldehyde condensation products sodium sulfonate, neopelex, lauryl sodium sulfate, potassium oleate, enuatrol, alkyl polyoxyethylene ether sulfonate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, alkylphenol-polyethenoxy base ether, Nonyl pheno base ether, polyoxyethylene polyoxypropylene base ether block copolymers, pull open powder, poly-second carboxylic esters sodium salt, one or more in alkylpolyoxyethylene phosphate or Fluhyzon first condensate sulfonates,

Wherein said thickener is selected from one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose or polyvinyl alcohol;

Wherein said stabilizing agent is selected from one or more in catechol, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, chloropropylene oxide, sodium sorbate, Sodium Benzoate, epoxidised soybean oil, linseed oil, quinhydrones, anthraquinone, eugenol, citric acid, hydroxy benzoate or nipasol;

Wherein said defoamer is chosen one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, C8-10 fat alcohol compound or II-ethylhexanol; Wherein silicone compound as organosilicon etc., as described in C10-20 saturated fat acid compounds as hendecanoic acid, tridecanoic acid, pentadecanoic acid etc., the C8-10 fat alcohol compound is as certain herbaceous plants with big flowers alcohol, ten alkanoic acids;

Wherein said antifreezing agent is selected from one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, sorbierite or urea;

Wherein said pH adjusting agent is selected from hydrogen-oxygen for one or more in sodium, ammoniacal liquor, acetic acid, citric acid or phosphoric acid; The consumption of pH adjusting agent is that to make the pH value of suspending agent be 5～9;

Wherein said bleeding agent is organosilicon, be selected from trisiloxanes, tetrasiloxane, many siloxanes one or more.

9. the insecticides that contains spiral shell worm ethyl ester claimed in claim 6, the preparation method who it is characterized in that suspending agent is as follows, spiral shell worm ethyl ester, Nitenpyram are mixed in above-mentioned ratio with dispersant, thickener, stabilizing agent, defoamer, antifreezing agent, bleeding agent, pH adjusting agent and water, in ball mill, ball milling is 2～3 hours, makes particle diameter all below the 5 μ m.

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CN106818798A (en) * 2016-12-15 2017-06-13 天津联合益农科技有限公司 A kind of compounded pesticides containing anabasine compound
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