General Motukoreaite Information
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Chemical Formula: |
Na2Mg38Al24(CO3)13(SO4)8(OH)108•56(H2O) |
Composition: |
Molecular Weight = 6,011.40 gm |
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Sodium 0.76 % Na 1.03 % Na2O |
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Magnesium 15.36 % Mg 25.48 % MgO |
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Aluminum 10.77 % Al 20.35 % Al2O3 |
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Hydrogen 3.69 % H 32.97 % H2O |
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Carbon 2.60 % C 9.52 % CO2 |
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Sulfur 4.27 % S 10.65 % SO3 |
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Oxygen 62.55 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Na2Mg38Al24(CO3)13(SO4)8(OH)108•56(H2O) |
Environment: |
Rim cement in volcanic breccias in weathered submarine environments. |
IMA Status: |
Approved IMA 1977 |
Locality: |
Brown's Island, (Motukorea) within Waitemata Harbor, New Zealand. Link to MinDat.org Location Data. |
Name Origin: |
Named for the Maori name for the locality (Motukorea - "island of the cormorants."). |
Name Pronunciation: |
Motukoreaite + Pronunciation |
Synonym: |
ICSD 29523 |
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PDF 41-1380 |
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Motukoreaite Image |
Images:
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Motukoreaite Crystallography
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Axial Ratios: |
a:c = 1:3.65351 |
Cell Dimensions: |
a = 9.172, c = 33.51, Z = 0.4; V = 2,441.37 Den(Calc)= 1.64 |
Crystal System: |
Trigonal - Hexagonal ScalenohedralH-M Symbol (3 2/m) Space Group: R 3m |
X Ray Diffraction: |
By Intensity(I/Io): 11.32(1), 3.72(0.7), 5.58(0.6),4.59(0.6), 2.58(0.4), 1.924(0.3), 2.39(0.3), |
Crystal Structure:
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drag1 - LMB Manipulate Structure
drag2 - RMB Resize/Rotate
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Rius J , Plana F , Neues Jahrbuch fur Mineralogie, Monatshefte , 1986 (1986) p.263-272, Contribution to the superstructure resolution of the double layer, mineral motukoreaite, Locality: the Emile Baudot bank, western Mediterranean
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Physical Properties of Motukoreaite
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Cleavage: |
{???} Perfect |
Color: |
Yellow green, White, Light yellow. |
Density: |
1.48 - 1.53, Average = 1.5 |
Habit: |
Fibrous - Crystals made up of fibers. |
Habit: |
Radial - Crystals radiate from a center without producing stellar forms (e.g. stibnite) |
Hardness: |
1-1.5 - Talc or a little harder |
Streak: |
white |
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Optical Properties of Motukoreaite
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Gladstone-Dale: |
CI meas= -0.377 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= -0.264 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.311,KPDmeas= 0.3389,KC= 0.2461 Ncalc = 1.36 - 1.4 |
Optical Data: |
Uniaxial (?), a=1.51, b=1.51, bire=0.0000. |
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Calculated Properties of Motukoreaite
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Electron Density: |
Bulk Density (Electron Density)=1.69 gm/cc note: Specific Gravity of Motukoreaite =1.64 gm/cc. |
Fermion Index: |
Fermion Index = 0.01 Boson Index = 0.99 |
Photoelectric: |
PEMotukoreaite = 1.05 barns/electron U=PEMotukoreaite x rElectron Density= 1.77 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Motukoreaite is Not Radioactive |
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Motukoreaite Classification
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Dana Class: |
17.01.07.01 (17)Compound Carbonates |
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(17.01)with miscellaneous formulae |
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(17.01.07)Dana Group |
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17.01.07.01 Motukoreaite Na2Mg38Al24(CO3)13(SO4)8(OH)108•56(H2O) R 3m 3 2/m |
Strunz Class: |
07.DD.35 07 - SULFATES (SELENATES, TELLURATES) |
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07.D - Sulfates (selenates, etc.) with additional anions, with H2O |
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07.DD -With only medium-sized cations; sheets of edge-sharing octahedra |
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07.DD.35 Carrboydite (Ni,Cu)14Al9(SO4,CO3)6(OH)43•7(H2O) Unk Hex |
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07.DD.35 Glaucocerinite (Zn,Cu)5Al3(SO4)1.5(OH)16•9(H2O) Unk (HEX-R) Trig |
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07.DD.35 Honessite Ni6Fe2(SO4)(OH)16•4(H2O) R 3m 3 2/m |
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07.DD.35 Hydrowoodwardite! Cu1-xAlx(OH)2(SO4)x/2•n(H2O)with0<x<0.67andn>3x/2 R 3m 3 2/m |
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07.DD.35 Zincowoodwardite! [Zn1-xAlx(OH)2][(SO4)x/2(H2O)n] P 3- or R 3m 3 |
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07.DD.35 Hydrohonessite Ni6Fe2(SO4)(OH)16•7(H2O) Unk Hex |
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07.DD.35 Motukoreaite Na2Mg38Al24(CO3)13(SO4)8(OH)108•56(H2O) R 3m 3 2/m |
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07.DD.35 Mountkeithite (Mg,Ni)11(Fe,Cr)3(SO4,CO3)3.5(OH)24•11(H2O) Unk Hex |
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07.DD.35 Shigaite Mn7Al4(SO4)2(OH)22•8(H2O) R 3 3 |
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07.DD.35 Natroglaucocerinite! (Na,Zn,Cu)10Al6(SO4)3(OH)32•18(H2O)? Unk |
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07.DD.35 Wermlandite (Ca,Mg)Mg7(Al,Fe)2(SO4)2(OH)18•12(H2O) P 3c1 3 2/m |
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07.DD.35 Nikischerite! NaFe6Al3(SO4)2(OH)18(H2O)12 R 3 3 |
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07.DD.35 Zincaluminite Zn6Al6(SO4)2(OH)26•5(H2O) Unk Hex |
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07.DD.35 Woodwardite Cu4Al2(SO4)(OH)12•2-4(H2O) Unk Hex |
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07.DD.35 Zincowoodwardite-3R! [Zn1BxAlx(OH)2][(SO4)x/2•n(H2O)],0.32<x<0.50,n=0.59 R 3m 3 2/m |
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07.DD.35 Zincowoodwardite-1T! [Zn1BxAlx(OH)2][(SO4)x/2•n(H2O)],x=0.33,n.0.96 P 3 3 |
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Other Motukoreaite Information
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References: |
NAME( Dana8) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Motukoreaite :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - EUROmin Project
4 - Ecole des Mines de Paris
5 - GeoScienceWorld
6 - Google Images
7 - Google Scholar
8 - Handbook of Mineralogy (MinSocAm)
9 - Handbook of Mineralogy (UofA)
10 - MinDAT
11 - Mineralienatlas (Deutsch)
12 - Online Mineral Museum
13 - QUT Mineral Atlas
14 - Ruff.Info
15 - WWW-MINCRYST
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Print or Cut-and-Paste your Motukoreaite Specimen Label here :
Motukoreaite
Na2Mg38Al24(CO3)13(SO4)8(OH)108•56(H2O)
Dana No: 17.01.07.01 Strunz No: 07.DD.35
Locality:
Notes:
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